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General : molecular solids
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 Message 1 of 5 in Discussion 
From: dredling  (Original Message)Sent: 7/27/2007 1:15 PM
Hi Steve,

A Question?: Which of the following is a molecular solid?

CaO
C10H22
C(graphite)
gold

I think the answer is C10H22, but I'm a little confused on what is a good way of telling which one is a molecular solid. What is the difference between a molecular solid and another solid?


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Reply
 Message 2 of 5 in Discussion 
From: MSN Nickname·Steve·Sent: 7/27/2007 6:08 PM
That's right, C10H22 is a hydrocarbon molecule of some kind, perhaps decane.  Each molecule of decane contains ten carbons and 22 hydrogen atoms.  Molecular compounds are not made of positive and negative ions, so we can eliminate CaO, and ionic compound.  The elements gold and carbon exist as extended networks of atoms bonded together in some kind of structure, but these networks are essentially infinite with no molecular unit.  A molecule consists of a specific number of atoms bonded together with covalent bonds.  As such, molecular compounds are usually made of nonmetallic elements.

The graphite and diamond forms of carbon are not molecular because there are no molecular units in these forms of carbon.  The atoms extend in practically an infinite array in the solid.  But buckyball, C60, is a molecular form of carbon, existing as soccer ball-shaped carbon molecules containing 60 carbon atoms specifically.  So if the question said "C(buckyball)" then that would have been molecular too.

Steve
 
 
 

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 Message 3 of 5 in Discussion 
From: MSN Nickname·Steve·Sent: 10/1/2007 3:39 PM
I was looking over some past messages and happened to notice in this question that I overlooked the word "solid" in the question.  Decane is a molecular compound all right, but it is not a solid at room temperature (its melting point is �?9.7°C).  So for the original question, which of the given compounds is a molecular solid, I would say none.  I don't think there is another isomer of decane that is a solid at room temperature either.
 
Graphite is a solid and is made of carbon atoms covalently bonded to each other like molecular compounds, but it has no definite formula, unlike molecular compounds.
 
Only two months too late....

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 Message 4 of 5 in Discussion 
From: MSN NicknameAbalo3Sent: 1/25/2008 4:43 PM
1. Which element has the highest first electron affinity between B, C, Li, N??

2. Is halogens a diatomic molecules?

3. Methane and oxygen react to form carbon dioxide and water. What mass of water if formed if 3.2g of methane reacts with 12.8g of oxygen to produce 8.8g of carbon dioxide?

4.Which one of these is not a solution: Brass, fog, hydrochloric acid and wine.

Reply
 Message 5 of 5 in Discussion 
From: MSN Nickname·Steve·Sent: 1/26/2008 12:25 AM
(See reply here.)

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