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Inorganic : reactions
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 Message 1 of 2 in Discussion 
From: dianna  (Original Message)Sent: 11/27/2004 7:47 AM
hi
i did an experiment, and found that the addition of NH3 does not cause a solution with Ni 2+ to form precipitate because it makes a water soluble complex. Would this be the right chemical reaction to describe it:
[Ni(H20)4]2+(aq) +6NH3(aq)---> [Ni(NH3)6]2+ +4H20?
 
and, if i wanted to write an equation to show that excess NaOH added to a solution with Al3+ ions formed water soluble complexes too, could i simply write:
Al3+ +4NaOH--> Al(OH)4-+ 4Na+?
 
thanx a bunch


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 Message 2 of 2 in Discussion 
From: MSN Nickname·Steve·Sent: 11/27/2004 6:56 PM
These look fine, except that Ni2+ ion exists as the bright green hexaaqua complex in aqueous solution, [Ni(H2O)6]2+.  Nickel also forms four-coordinate complexes, such as the tetrahedral [NiCl4]2- ion and the square planar [Ni(CN)4]2- ion.  The latter is the more common geometry for four-coordinate d8 transition metal complexes, and may be the reason your textbook may have assumed this to be the case for the Ni2+(aq) ion also.
 
 
Steve