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Organic : Alkenes and Alkynes
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 Message 1 of 2 in Discussion 
From: MSN Nicknamekathy_4ever2006  (Original Message)Sent: 6/16/2006 3:00 PM
hi there thanks so much for helping me! but I was wondering anything I need to know about naming and drawing Alkenes and Alkynes????? like any steps I follow ? are they similar to the alkanes?    
 
      Thanks you rock!


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 Message 2 of 2 in Discussion 
From: MSN Nickname·Steve·Sent: 6/17/2006 12:44 AM
Hi Kathy, yes, the procedure is very similar, except that you have to indicate where the double or triple bond is.  When you begin by finding and numbering the carbons in the main chain, always start from the end that has the double or triple bond closest to it, not which just has a group closest to it.  So that simplifies things.
 
CH3CH2CH2CH=CH2     This is 1-pentene.

The "1" means the double bond starts on carbon 1 of the main chain.  We also changed the name ending from "ane" to "ene" since this is an alkene.

       CH3
       |
CH3CHCH2CHCH2CH2CH=CH2     This is 5,7-dimethyl-1-octene.
                 |
                 CH3
 
Getting the right number of hydrogens on the carbons takes a little practice when writing condensed structural formulas like these.  When in doubt, draw your structure showing all of the bonds, C-to-C and C-to-H (remember, always have four bonds on carbon!).
 
 
When the double bond is not on the end, you have cis and trans isomeric possibilities:
 

     CH3    CH3               CH3     H                            CH3    H
       \      /                       \      /                                 \      /
        C=C                        C=C                                   C=C
       /      \                       /      \                                 /      \
     H        H                   H       CH3                          CH3    H
  cis-2-butene              trans-2-butene               2-methyl-1-propene
                                                                     (has no cis or trans isomers)
 
cis = "on the same side" of the double bond,  trans = "on opposite sides" of the double bond as drawn above.
 
 
Alkynes follow the same rules, but there are no cis-trans isomers.  (BTW the words cis and trans are alway italicized.  )

CH3CH2CCH            CH3CCCH3
     1-butyne                      2-butyne
 
Since these are alkynes, the parent name ends in "yne".
 

             CH2CH3
             |
CH3CH2CHCH2CHCCCH2CH3      This is 7-ethyl-5-methyl-3-nonyne.
                       |
                      CH3
 
 
 
That's the general idea!

Steve