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Organic : alkanes
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 Message 16 of 24 in Discussion 
From: MSN Nickname·Steve·  in response to Message 15Sent: 6/1/2006 3:03 AM
Hey, how's it going in the world of alkanes? 
 
That's right, the longest chain has seven carbons which is heptane so that is the parent name.
 
                CH3
 1      2     3|   4       5     6       7
CH3–CH2–C–CH2–CH–CH2–CH3
                |           |
                CH2      CH3
                 |
                CH3
 
Now which end to start numbering from, since there is a group attached to third carbon from either end, we break the tie by seeing which end a second group is closest to, which is the left end (there is a methyl group and an ethyl group attached to the third carbon from that end).  The other methyl group is on carbon 5.  So the alkane is 3-ethyl-3,5-dimethylheptane.
 
 
BTW there is another chain that has seven carbons:
 
                CH3
               3|   4       5     6       7
CH3–CH2�?/FONT>C–CH2–CH–CH2–CH3
                         |
             2 CH2      CH3
                |
             1 CH3
 
But this gives the same result, 3-ethyl-3,5-dimethylheptane, so it makes no difference in this case.
 
 
For the group names, just memorize the common ones and that'll make things a lot easier!
 
––CH3   =   methyl           \
                                      |  These are the "big two" that you see most often.
––CH2�?/FONT>CH3   =   ethyl     /
 
––CH2�?/FONT>CH2�?/FONT>CH3   =   propyl
 
    CH3
     |
––CH–CH3   =   isopropyl
 
etc.
 
 
Steve


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     re: alkanes   MSN Nicknamekathy_4ever2006  6/10/2006 9:09 PM