Hi, I'm having a bit of problem
In alkaline solution V(V) occurs as the oxoion VO4 3-. In acidic solution V(V) occurs as the oxoion VO2+. Addition of hydrogen peroxide to an acidic solution of VO2+ results in formation of the mono peroxo vanadium(V) ion, [V(O2)O]+. this species is charged and therefore soluble in water. It is not soluble in organic solvents.
So... my problems are I can't figure out what I would get in the following reagents:
V(V) + NaOH (initially) = is it VO4 3-?
V(V) + Na OH (excess) = VO4 3-??
V(V) + NaOH + H2O2 = I have no idea
V(V) + H + H2O2 = I'm guessing [V(O2)O]+
Could you help me?
Thanx |
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