MSN Home  |  My MSN  |  Hotmail
Sign in to Windows Live ID Web Search:   
go to MSNGroups 
Free Forum Hosting
 
Important Announcement Important Announcement
The MSN Groups service will close in February 2009. You can move your group to Multiply, MSN’s partner for online groups. Learn More
Chemistry Corner[email protected] 
  
What's New
  
  Welcome Page  
  About This Site  
  Message Boards  
  General  
  Inorganic  
  Organic  
  Pictures  
  Random  
  FOR ALL  
  Handy Symbols  
  Chemistry Humor  
    
  Documents  
  Chemistry Sites I  
  Chemistry Sites II  
  Chemistry Sites III  
  Organic Sites I  
  Organic Sites II  
  Analytical Sites I  
  Analytical Sites II  
  Lesson Plan Sites  
  Online Problems  
  Names & Formulas  
  Naming Exercises  
  Equations I  
  Equations II  
  Eq. Exercises I  
  Eq. Exercises II  
  The Mole I  
  The Mole II  
  Mole Exercises  
  Stoichiometry  
  Stoich. Exercises  
  More Communities  
  School's Out!  
  _________________  
  Site Map  
  
  
  Tools  
 
Organic : Dibenzalacetone synthesis
Choose another message board
View All Messages
  Prev Message  Next Message       
Reply
 Message 4 of 4 in Discussion 
From: MSN Nickname·Steve·  in response to Message 3Sent: 4/9/2008 6:27 AM
Ah, yes, you're right, I overlooked the acetone.  Well, if an acetone-water mixture was the solvent, I would assume that there would be a lot of excess acetone present, and you would no longer have a two-to-one molar ratio of benzaldehyde to acetone to start with.  (I just noticed that the description says, "benzaldehyde + 2 moles of acetone," but it should be the other way around.)
 
Other than that, it is true that the acetone could hinder crystallization of the product, depending on how much acetone was present.  In that case, the mixture could be heated for an extra period of time to drive off the more volatile acetone.  (An acetone-water mixture is great for slow crystallization of water-insoluble organic solids.  Dissolve the compound in acetone, add water just to the point of causing precipitation, and then let the acetone slowly evaporate overnight by leaving the container uncovered.)
 
Steve